1. Industrial pure titanium
This kind of material is not an alloy, but titanium containing a small amount of oxygen, iron and other impurities.
Example: CP Grade 1, Grade 2, Grade 3, Grade 4 (the larger the number, the higher the intensity)
Main features:
Low strength: The strength is the lower of all titanium materials, which is comparable or slightly lower than ordinary steel.
Good corrosion resistance: especially in oxidizing environments (such as seawater and chlorine environments), its corrosion resistance is better than that of most titanium alloys.
Good plasticity: easy to cold process and form.
Application scenario:
It is mainly used in situations where strength requirements are not high, but high corrosion resistance is required, such as certain non-load-bearing structural parts of chemical equipment and marine platforms.
It is not commonly used in the manufacture of high-strength structural screws.
2. α-type and near-α-type titanium alloys
The main characteristics of this type of alloy are stable organization, good heat resistance, and excellent welding performance.
Example: Ti-5Al-2.5Sn, Ti-0.3 Mo-0.8Ni
Main features:
It cannot be strengthened by heat treatment, and is usually used in an annealed state.
It has good high temperature performance and creep strength.
Moderate strength.
Application scenario:
It is mainly used for high-temperature components (such as engine compressor housings) in the aerospace field.
It is not common in screw applications, unless there are special high temperature resistance or welding requirements.
3. (α+β) titanium alloy
This is the main material category commonly used in the manufacture of high-strength titanium alloy screws. They can be significantly strengthened by solution and aging treatment to achieve high strength.
3.1 Universal (α+β) alloy
Example: Ti-6Al-4V (Grade 5)
This is because the use of titanium alloy screws accounts for more than 90% of all titanium alloy fasteners.
Features: It has excellent overall performance, high strength, good fatigue performance, good corrosion resistance, and mature technology.
Application: From aerospace, industry to high-end bicycles, racing cars, medical implants, etc., it is widely used.
Example: Ti-6Al-4V ELI (low clearance)
Features: It is a high-purity version of Ti-6Al-4V, which reduces the content of gap elements such as oxygen and nitrogen, and has better toughness and plasticity, especially at low temperatures.
Application: Mainly used in fields with high fracture toughness requirements, such as medical implants (artificial joints, bone plate screws), and low-temperature pressure vessels.
3.2 Heat-treatable reinforced (α+β) alloy
Such alloys can retain more metastable β phases after quenching, thereby obtaining high strength during aging.
Example: Ti-5Al-2Sn-2Zr-4Mo-4Cr (Ti-17)
Features: It has a combination of high strength and good toughness, and good deep hardenability.
Application: Mainly used for high-strength structural parts of aviation engines, but also for the manufacture of screws with high requirements.
3.3 High-strength and high-toughness (α+β) alloy
Example: Ti-6Al-2Sn-2Zr-2Mo-2Cr-0.25Si (Ti-62222S)
Features: It maintains good toughness and stress corrosion resistance at a higher strength level.
Application: Aerospace main bearing structural parts, high-strength screws in environments sensitive to stress corrosion.
4. β-type titanium alloy
This kind of alloy contains a large number of β-stable elements, and all β-phase tissues can be obtained after quenching. It has good plasticity and is easy to cold process.Through aging treatment, fine α phases can be precipitated and high strength can be obtained.
Example: Ti-3Al-8V-6Cr-4Mo-4Zr (Beta C), Ti-15V-3Cr-3Sn-3Al (Ti-15-3), Ti-13V-11Cr-3Al
Main features:
Good cold formability: it is very soft in the solid solution state, and can be directly cold-headed, and the cost of manufacturing screws is low.
High strength: after aging treatment, the strength can reach 1100-1400 MPa or even higher.
Good corrosion resistance: especially the corrosion resistance to reducing acids is better than that of Ti-6Al-4V.
Application scenario:
It is mainly used in the manufacture of high-performance aerospace fasteners, as well as fields with high requirements for strength and weight loss.
In the medical field, certain β alloys are used in the manufacture of bone screws because of their low elastic modulus (closer to human bone) and good biocompatibility.
Conventional applications: Ti-6Al-4V (Grade 5) is preferred, which is cost-effective and has balanced performance.
Medical implantation: Ti-6Al-4V ELI or β alloy with better biocompatibility is preferred.
High-strength/weight-loss requirements: Consider high-strength (α+β) alloys (such as Ti-62222S) or β alloys (such as Beta C).
Consider cost for mass production: consider cold-heading β alloys (such as Ti-15-3), which can save processing costs.
